ADDITION OF GRIGNARD REAGENTS TO 1-ACYL-4-METHOXYPYRIDINIUM SALTS. AN APPROACH TO THE SYNTHESIS OF QUINOLIZIDINONES.

DOI: 10.1016/S0040-4039(00)85000-5

Source and publish data:

Tetrahedron Letters p. 4549 - 4552 (1986)

Update date:2022-07-31

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Authors:

Comins, Daniel L.

Brown, Jack D.

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Article abstract of DOI:10.1016/S0040-4039(00)85000-5

The addition of Grignard reagents to 1-acyl-4-methoxypyridinium salts gives 2-substituted 1-acyl-2,3-dihydropyridones.This reaction was utilized to synthesize (+/-)-epi-myrtine and trans-4-phenylquinolizidin-2-one.

Full text of DOI:10.1016/S0040-4039(00)85000-5

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