Chemistry Letters p. 885 - 888 (1989)
Update date:2022-09-26
Topics:
Setsune, Jun-ichiro
Iida, Toshiya
Kitao, Teijiro
Cobalt(III) porphyrins reacted with α-diazo-β-dicarbonyl compounds to give N,Co-methano bridged Co(III) porphyrins in good yields.The axial ligand and the peripheral substituents have great influence on the insertion of the carbenes and on the subsequent transformation to Co(III) N-alkylporphyrins with a
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