Tetrahedron Letters p. 2093 - 2096 (1985)
Update date:2022-08-04
Topics:
Ito, Yoshikatsu
Ji-Ben, Meng
Suzuki, Shin
Kusunaga, Yoshitaka
Matsuura, Teruo
Fukuyama, Keiichi
In contrast to simple imidazoles, 1-methyl-2,4,5-triphenylimidazole (1) produced stable oxetane photoadducts 3b-e with good efficiency upon irradiation in the presence of benzophenone derivatives 2b-e in acetonitrile solution.Irradiation in the solid-phase was also studied.The oxetanes 3b-e readily underwent cycloreversion by acid catalysis or by heating.
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