OXIDATION OF 1,2,3-BUTATRIENES: A FACILE FORMATION OF METHYLENECYCLOPROPANONES AND THEIR SUBSEQUENT PHOTODECARBOXYLATION

DOI: 10.1016/S0040-4039(00)87808-9

Source and publish data:

Tetrahedron Letters p. 6357 - 6360 (1986)

Update date:2022-08-04

Topics:

Authors:

Ando, Wataru

Hayakawa, Hiroshi

Tokitoh, Norihiro

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Article abstract of DOI:10.1016/S0040-4039(00)87808-9

A peracid oxidation of some sterically hindered 1,2,3-butatrienes (4) using an alkaline biphasic solvent system was examined, and the resulted methylenecyclopropanones (5) were readily photodecarboxylated to give the corresponding allenes (6) in good yiel

Full text of DOI:10.1016/S0040-4039(00)87808-9

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