Journal of Organic Chemistry p. 3435 - 3441 (1987)
Update date:2022-08-03
Topics:
Hwang, Ki-Jun
Logusch, Eugene W.
Brannigan, Lawrence H.
High field NMR and X-ray crystallographic methods were used to elucidate the diastereoselectivity of 1,2-addition of lithiated N-(trialkylsilyl)methylphenylsulfoximines to aldehydes.The resulting (β-hydroxyalkyl)sulfoximines were readily cyclized with phosgene to yield the novel sulfoximine-derived 1,4,3-oxathiazin-2(6H)-one 4-oxides.
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