ORGANO-RUTHENABORANE AND -OSMABORANE CLUSTER COMPOUNDS: PREPARATION AND NMR STUDIES OF 6-C6Me6)-nido-6-MB9H13> (M=Ru, Os) AND THE REARRANGED CLUSTER 6-C6Me6)-nido-5-RuB9H11-7-(PMe2Ph)>

DOI: 10.1016/0022-328X(87)80403-5

Source and publish data:

Journal of Organometallic Chemistry p. 233 - 246 (1987)

Update date:2022-08-04

Topics:

Authors:

Bown, Mark

Fontaine, Xavier L. R.

Greenwood, Norman N.

Kennedy John D.

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Article abstract of DOI:10.1016/0022-328X(87)80403-5

Reaction of the versatile organometallaborane synthon <(η⁶-C6Me6)RuCl2>2 with arachno-(1-) affords <6-(η⁶-C6Me6)-nido-6-RuB9H13> in 80percent yield.An analogous reaction with <(η⁶-C6Me6)OsCl2>2 (here reported for th

Full text of DOI:10.1016/0022-328X(87)80403-5

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Product name:C₆(CH₃)6RuB₉H₁₁P(C₆H₅)3

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