SYSNTHESIS OF (CH3C(CH2PPh2)3)CoL COMPLEXES (L=O2CO, S2CO, O2SO) THROUGH METAL-ASSISTED CO2, CS2, SO2 OXIDATION. CRYSTAL STRUCTURE OF (CH3C(CH2PPh2)3)Co(O2SO)

DOI: 10.1016/0022-328X(87)87136-X

Source and publish data:

Journal of Organometallic Chemistry p. C5 - C9 (1987)

Update date:2022-09-26

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Authors:

Cecconi, Franco

Ghilardi, Carlo A.

Midollini, Stefano

Moneti, Simonetta

Orlandini, Annabella

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Article abstract of DOI:10.1016/0022-328X(87)87136-X

The solution obtained by reduction of <(triphos)Co(μ-Cl)2Co(triphos)>²⁺ (triphos=CH3C(CH2PPh2)3) with Na/Hg reacts with CO2, CS2 and SO2 to give (triphos)Co(O2CO), (triphos)Co(S2CO), and (triphos)Co(O2SO), respectively.The molecular structure o

Full text of DOI:10.1016/0022-328X(87)87136-X

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