Synthesis of C-Glycosides of 3-Deoxy-D-manno-2-octulosonic Acid. Stereoselectivity in an Enolane Reaction

DOI: 10.1021/jo00226a010

Source and publish data:

Journal of Organic Chemistry p. 3777 - 3784 (1987)

Update date:2022-07-30

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Authors:

Luthman, Kristina

Orbe, Martin

Waglund, Tommy

Claesson, Alf

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Article abstract of DOI:10.1021/jo00226a010

Eight different C-glycosidic derivatives of 3-deoxy-D-manno-2-octulosonic acid (KDO) were prepared by reacting the enolate of methyl of ethyl 2,6-anhydro-3-deoxy-4,5:7,8-di-O-isopropylidene-D-glycero-D-talo-(or galacto)octanate (7a,b and 22) with the elec

Full text of DOI:10.1021/jo00226a010

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