THE REACTION OF CARBONYL COMPOUNDS WITH DIIODOMETHANE IN THE PRESENCE OF SAMARIUM: NOVEL SYNTHESES OF IODOHYDRINS AND CYCLOPROPANOLS

DOI: 10.1016/S0040-4039(00)84764-4

Source and publish data:

Tetrahedron Letters p. 3243 - 3246 (1986)

Update date:2022-08-04

Topics:

Authors:

Imamoto, Tsuneo

Takeyama, Toshiaki

Koto, Hiroyasu

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Article abstract of DOI:10.1016/S0040-4039(00)84764-4

The iodomethylation of carbonyl compounds giving iodohydrins has been achieved under ordinary conditions by the use of diiodomethane and samarium.A novel synthesis of cyclopropanols from α-haloketones or 1,2-dibenzoylethane is also described.

Full text of DOI:10.1016/S0040-4039(00)84764-4

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