ASYMMETRIC SYNTHESIS OF (R)-(+)- AND (S)-(-)-2,2,4-TRIMETHYL-4-(HYDROXYMETHYL)-1,3-DIOXOLANE OF HIGH ENANTIOMERIC PURITY

DOI: 10.1016/S0040-4020(01)96082-X

Source and publish data:

Tetrahedron p. 5985 - 5990 (1986)

Update date:2022-08-04

Topics: Asymmetric synthesis Catalysts Stereochemistry Enantiomeric purity Chiral reagents

Authors:

Tanner, David

Somfai, Peter

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4020(01)96082-X

The title compounds, 1 and 1', are readily available in four steps from 2-benzyloxymethyl-2-propen-1-ol, the key step being Sharpless asymmetric epoxidation to give the chiral epoxides 5 or 5'.The total chemical yield of 1 or 1' is 50percent, the final pr

Full text of DOI:10.1016/S0040-4020(01)96082-X

Products guided by the article

Product name:(R)-[2-(benzyloxymethyl)oxiran-2-yl]methanol

Cas No:109240-65-5

R&D Labs maybe for 109240-65-5

Wuhan Pengo Technology.,Ltd.

Contact:+86-27-67841589

Address:Add: 999 Gaoxin Road, Donghu New Technology Development Zone, Wuhan City, Hubei, China
Huangshi Shennong Chemical Technology Co., Ltd

Contact:+86-714-3072290

Address:Eastern industrial park , Tieshan district , Huangshi city ,Hubei province , China
Shanghai AoBo Bio-Pharmaceutical Technology Co., Ltd.

Contact:+86-21-51320130-801, 816

Address:Room 601, No. 1011, Halei Road, Zhangjiang High-Tech Park, Pudong, Shanghai
Anhui Eapearl Chemical Co., Ltd.

Contact:86-562-5858458

Address:358 South Huaihe Road
Zibo Linzi Darong Fine Chemical Co., Ltd(expird)

Contact:86-532-67773200; 15689126900

Address:Qidu town,Linzi district,Zibo city,Shandong province,China

Relevant to this article

A Pulse Radiolytic Study of the Acid Dissociation of OH Protons in Radicals Related to Salicylic Acid

Doi:10.1021/j100301a032
(1987)
Doi:10.1021/ja01532a039
(1959)
FUNCTIONALISATION OF SATURATED HYDROCARBONS. Part X. A COMPARATIVE STUDY OF CHEMICAL AND ELECTROCHEMICAL PROCESSES (GIF AND GIF-ORSAY SYSTEMS) IN PYRIDINE, IN ACETONE AND IN PYRIDINE-CO-SOLVENT MIXTURES

Doi:10.1016/S0040-4020(01)85889-0
(1988)
Intramolecular Diels-Alder Reactions of 1,2,4-Triazines. Synthesis of Condensed Pyrimidines

Doi:10.1021/jo00228a024
(1987)
The first asymmetric synthesis of all four isomers of cis- and trans-3,4-dihydroxy-3,4-dihydromollugin

Doi:10.1016/j.tetlet.2008.09.138
(2008)
3,4-Disubstituted-1,2,3,4,5,6,7,8-octahydroquinazoline-2-thiones: Synthesis, antimicrobial evaluation and QSAR investigations using Hansch analysis

Doi:10.1002/ardp.200700153
(2008)

Article Doi