ASYMMETRIC SYNTHESIS OF (R)-(+)- AND (S)-(-)-2,2,4-TRIMETHYL-4-(HYDROXYMETHYL)-1,3-DIOXOLANE OF HIGH ENANTIOMERIC PURITY

DOI: 10.1016/S0040-4020(01)96082-X

Source and publish data:

Tetrahedron p. 5985 - 5990 (1986)

Update date:2022-08-04

Topics: Asymmetric synthesis Catalysts Stereochemistry Enantiomeric purity Chiral reagents

Authors:

Tanner, David

Somfai, Peter

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Article abstract of DOI:10.1016/S0040-4020(01)96082-X

The title compounds, 1 and 1', are readily available in four steps from 2-benzyloxymethyl-2-propen-1-ol, the key step being Sharpless asymmetric epoxidation to give the chiral epoxides 5 or 5'.The total chemical yield of 1 or 1' is 50percent, the final pr

Full text of DOI:10.1016/S0040-4020(01)96082-X

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