Regioselectivity of Addition of Thiols and Amines to Conjugated Allenic Ketones and Esters

DOI: 10.1021/jo00226a012

Source and publish data:

Journal of Organic Chemistry p. 3789 - 3793 (1987)

Update date:2022-08-04

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Authors:

Sugita, Toshio

Eida, Mitsuru

Ito, Hiroshi

Komatsu, Naoki

Abe, Kazuaki

Suama, Masakazu

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Article abstract of DOI:10.1021/jo00226a012

Regioselectivity of nucleophilic addition to conjugated allenic ketones depends strongly on the nucleophile: anionic nucleophiles, e.g., triethylamine salts of benzenethiols, gave the β-substituted β,γ-unsaturated ketones with high selectivity.In contrast

Full text of DOI:10.1021/jo00226a012

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