Organic Letters p. 197 - 199 (2009)
Update date:2022-08-04
Topics:
Higuchi, Kazuhiro
Sato, Yukihiro
Tsuchimochi, Mei
Sugiura, Kenta
Hatori, Masatoshi
Kawasaki, Tomomi
We have accomplished the first total synthesis of (±)-hinckdentine A (1). The key steps are m-CPBA oxidation of 2-arylindole followed by acid-mediated Mannich-type C-C bond formation of 2-hydroxyindolin-3-one, seven-membered ring closure, and regioselecti
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