Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 211 - 218 (1987)
Update date:2022-09-26
Topics: Ozonolysis
Forrester, Alexander R.
Purushotham, Vemishetti
Potassium ozonate has been prepared by reaction of ozone with potassium superoxide dispersed in Freon-12.Orange solutions of potassium ozonate in benzene or toluene containing 18-crown-6 react with nitrone traps to give spin adducts mainly derived from the oxide radical anion, which is a decomposition product of the ozonate radical anion.With 2-methyl-2-nitrosopropane in toluene solution the ozonate gives five nitroxide radicals in whose formation the oxide radical anion is again implicated.With nitrosobenzene electron transfer occurs.Comparable reactions with superoxide are described.
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