Biradical Reversion in the Intramolecular Photochemistry of Carbonyl-Substituted 1,5-Hexadienes

DOI: 10.1021/ja00252a031

Source and publish data:

Journal of the American Chemical Society p. 5491 - 5497 (1987)

Update date:2022-08-04

Topics:

Authors:

Schroeder, Clemens

Wolff, Steven

Agosta, William C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00252a031

We have studied the intramolecular photochemistry of dienones 10a,b-12a,b.The initial rate of loss of alkene stereochemistry in recovered starting ketone provides a measure of the rate of reversion (k_r) of the biradical intermediate (SchemeI) r

Full text of DOI:10.1021/ja00252a031

Products guided by the article

Product name:6-Octen-2-one, 3-methylene-, (Z)- (9CI)

Cas No:109669-37-6

R&D Labs maybe for 109669-37-6

Anhui Biochem United Pharmaceutical Co., Ltd.

Contact:0086 551 5167062 / 5228268

Address:No. 30 Hongfeng Road, Hi-Tech Development Zone, Hefei (230088), China
Jinan Trio PharmaTech Co., Ltd

Contact:86-531-88811783；+(0)13153010282

Address:2766 Yingxiu Road, Jinan High-Tech Zone, China
Shanghai Kangxin Chemical Co., Ltd

Contact:+86 21 60717227

Address:118,Ganbai Village,Waigang Town,Jiading District,Shanghai
Fusilin chemical science & technology co., ltd.

Contact:532-80698166/86057573, +86-400-669-7885

Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
Rely Chemicals Ltd.

Contact:+86-518-81061113

Address:No. 8 Lingzhou Road, Lianyungang, Jiangsu, China

Relevant to this article

Facile synthesis of bicyclo orthoesters and bicyclo amide acetals using α,α-difluoroalkylamines

Doi:10.1055/s-0028-1083145
(2008)
A convenient synthesis and biological activity of novel pyrido[4,3-d]pyrimidin-4(3H)-ones

Doi:10.1002/jhet.2119
(2015)
Design, synthesis, and anticancer evaluation of long-chain alkoxylated mono-carbonyl analogues of curcumin

Doi:10.1016/j.ejmech.2015.08.036
(2015)
Thromboxane synthase inhibitors. Synthesis and pharmacological activity of (R)-, (S)-, and (±)-2,2-dimethyl-6-[2-(1H-imidazol-1-yl)-1-[[(4 methoxyphenyl)-methoxy]methyl]ethoxy]hexanoic acids

Doi:10.1021/jm00393a022
(1987)
Inhibiteurs mixtes des voies de la cyclooxygenase et des lipoxygenases: synthese et activite de derives hydrazoniques

Doi:10.1016/0223-5234(87)90010-9
(1987)
Inhibition of 3-phosphoglycerate dehydrogenase (PHGDH) by indole amides abrogates de novo serine synthesis in cancer cells

Doi:10.1016/j.bmcl.2019.07.011
(2019)

Article Doi