
Journal of the American Chemical Society p. 5491 - 5497 (1987)
Update date:2022-08-04
Topics:
Schroeder, Clemens
Wolff, Steven
Agosta, William C.
We have studied the intramolecular photochemistry of dienones 10a,b-12a,b.The initial rate of loss of alkene stereochemistry in recovered starting ketone provides a measure of the rate of reversion (kr) of the biradical intermediate (SchemeI) r
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Doi:10.1055/s-0028-1083145
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