Biradical Reversion in the Intramolecular Photochemistry of Carbonyl-Substituted 1,5-Hexadienes

DOI: 10.1021/ja00252a031

Source and publish data:

Journal of the American Chemical Society p. 5491 - 5497 (1987)

Update date:2022-08-04

Topics:

Authors:

Schroeder, Clemens

Wolff, Steven

Agosta, William C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00252a031

We have studied the intramolecular photochemistry of dienones 10a,b-12a,b.The initial rate of loss of alkene stereochemistry in recovered starting ketone provides a measure of the rate of reversion (k_r) of the biradical intermediate (SchemeI) r

Full text of DOI:10.1021/ja00252a031

Products guided by the article

Product name:6-Octen-2-one, 3-methylene-, (Z)- (9CI)

Cas No:109669-37-6

R&D Labs maybe for 109669-37-6

Chengdu D-Innovation Pharmaceutical Co., Ltd

Contact:86-28-85105536

Address:1001, B6, No.88 Keyuan South Road, Chengdu Hi-Tech Zone
ZHIJIANG ZENVA SINO COMMERCE AND TRADE CO., LTD.

website:http://www.zenvasino.com

Contact:+86-138-72658998

Address:Shibeishan Road,Zhijiang, Hubei, China
Jinan Boss Chemical Industry Co., Ltd.【revoke the business license】

website:http://www.chemboss.com.cn

Contact:+86-531-58591595

Address:No2.Hualong Road, Jinan, China
Luzhou North Chemical Co., Ltd.

Contact:+86-830-2796784；+86-830-2796776

Address:Gaoba, Longmatan District, Luzhou, Sichuan Province
Anhui New Star Pharmaceutical Development Co., Ltd

Contact:013956922763

Address:Floor 3, F9A, F Workshop, No.110 Kexue Road, High-Tech Development Zone, Hefei, Anhui ,China

Relevant to this article

Facile synthesis of bicyclo orthoesters and bicyclo amide acetals using α,α-difluoroalkylamines

Doi:10.1055/s-0028-1083145
(2008)
A convenient synthesis and biological activity of novel pyrido[4,3-d]pyrimidin-4(3H)-ones

Doi:10.1002/jhet.2119
(2015)
Design, synthesis, and anticancer evaluation of long-chain alkoxylated mono-carbonyl analogues of curcumin

Doi:10.1016/j.ejmech.2015.08.036
(2015)
Thromboxane synthase inhibitors. Synthesis and pharmacological activity of (R)-, (S)-, and (±)-2,2-dimethyl-6-[2-(1H-imidazol-1-yl)-1-[[(4 methoxyphenyl)-methoxy]methyl]ethoxy]hexanoic acids

Doi:10.1021/jm00393a022
(1987)
Inhibiteurs mixtes des voies de la cyclooxygenase et des lipoxygenases: synthese et activite de derives hydrazoniques

Doi:10.1016/0223-5234(87)90010-9
(1987)
Inhibition of 3-phosphoglycerate dehydrogenase (PHGDH) by indole amides abrogates de novo serine synthesis in cancer cells

Doi:10.1016/j.bmcl.2019.07.011
(2019)

Article Doi