Biradical Reversion in the Intramolecular Photochemistry of Carbonyl-Substituted 1,5-Hexadienes

DOI: 10.1021/ja00252a031

Source and publish data:

Journal of the American Chemical Society p. 5491 - 5497 (1987)

Update date:2022-08-04

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Authors:

Schroeder, Clemens

Wolff, Steven

Agosta, William C.

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Article abstract of DOI:10.1021/ja00252a031

We have studied the intramolecular photochemistry of dienones 10a,b-12a,b.The initial rate of loss of alkene stereochemistry in recovered starting ketone provides a measure of the rate of reversion (k_r) of the biradical intermediate (SchemeI) r

Full text of DOI:10.1021/ja00252a031

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