ETUDE CINETIQUE DE L'AMINOLYSE EN MILIEU NON AQUEUX D'ESTERS MODELES DE PEPTIDYL-t-ARN; INFLUENCE D'UN GROUPE HYDROXYLE VOISIN

DOI: 10.1016/S0040-4020(01)91179-2

Source and publish data:

Tetrahedron p. 327 - 337 (1984)

Update date:2022-08-03

Topics: Hydroxyl group Aminolysis Kinetic Study Esters Influence Non-aqueous medium

Authors:

Julia, Marc

Mestdagh, Helene

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Article abstract of DOI:10.1016/S0040-4020(01)91179-2

n-Butylaminolysis of cis 2-hydroxy-cyclopentyl benzoylglycinate (a simple model of peptidyl-t-RNA) in MeCN occurs ca 300 times faster than that of cyclopentyl benzoylglycinate.This acceleration caused by the neighbouring cis 2-hydroxy group is considerabl

Full text of DOI:10.1016/S0040-4020(01)91179-2

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