Tetrahedron p. 327 - 337 (1984)
Update date:2022-08-03
Topics: Hydroxyl group Aminolysis Kinetic Study Esters Influence Non-aqueous medium
Julia, Marc
Mestdagh, Helene
n-Butylaminolysis of cis 2-hydroxy-cyclopentyl benzoylglycinate (a simple model of peptidyl-t-RNA) in MeCN occurs ca 300 times faster than that of cyclopentyl benzoylglycinate.This acceleration caused by the neighbouring cis 2-hydroxy group is considerabl
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