Electron-transfer Platinum Complexes of Esters of Dithiocarbazic Acid. The Crystal and Molecular Structure of

DOI: 10.1039/DT9870001035

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Journal of the Chemical Society, Dalton Transactions p. 1035 - 1040 (1987)

Update date:2022-08-05

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Authors:

Fares Vincenzo

Giuliani, Anna Maria

Imperatori, Patrizia

Suber, Lorenza

Tarli, Franco

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Article abstract of DOI:10.1039/DT9870001035

The ligand behaviour of the esters of dithiocarbazic acid NHRNHC(=S)SR' in intensely coloured complexes containing the doubly deprotonated ligands (R = H, R' = CH2Ph; R = CH2Ph, R' = Me or CH2Ph; R = Prⁱ, R' = Me; R = hexyl, R'= Me or CH2Ph) has been investigated by electronic, i.r., and 1H n.m.r. spectroscopy and electrochemistry.The crystal and molecular structure of has also been determined.All the complexes have a square-planar trans-PtN2S2 chromophore; they are dithiolene-like and show electron-transfer properties.

Full text of DOI:10.1039/DT9870001035

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