
Journal of the Chemical Society. Perkin transactions I p. 1417 - 1424 (1986)
Update date:2022-08-05
Topics:
Blackburn, G. Michael
Parratt, Martin J.
A new general synthesis of α-fluorovinylphosphonates is provided by a Wadsworth-Emmons condensation of tetra-alkyl fluoromethylenebisphosphonates (1) with aldehydes and ketones.The reaction shows useful stereoselectivity favouring the less-hindered alkene
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