Tetrahedron Letters p. 5177 - 5180 (1986)
Update date:2022-08-02
Topics:
Winkler, Jeffrey D.
Hershberger, Paul M.
Springer, James P.
We describe herein the first stereoselective synthesis of the natural (-)-histrionicotoxin ring system, where the chirality is derived from L-glutamic acid.The key transformation involves intramolecular dioxolenone photocycloaddition of a substrate derive
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