Tetrahedron Letters p. 275 - 278 (1987)
Update date:2022-08-04
Topics:
Squillacote, Michael E.
Bergman, Adelle
Felippis, James De
West, Elizabeth M.
The thermal decay of oxadiaziridines (ODZs) photochemically generated from a series of bicyclic azoxy compounds is examined.The thermal reversion of exo ODZs to the starting azoxy compounds shows a significant rate enhancement.These reactions appear to be examples of anchimeric assistance by homoallylic Π bonds involving only neutral species.
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