CHEMOSELECTIVE SYNTHESIS OF HOMOALLYLIC FLUORIDES FROM CYCLOPROPYLMETHANOLS BY RING OPENING

DOI: 10.1016/S0040-4039(00)95807-6

Source and publish data:

Tetrahedron Letters p. 663 - 666 (1987)

Update date:2022-07-30

Topics: Synthesis Nucleophile Electrophile Reaction Conditions Chemoselectivity Ring Opening Chemoselective synthesis

Authors:

Kanemoto, Shigekazu

Shimizu, Makoto

Yoshioka, Hirosuke

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Article abstract of DOI:10.1016/S0040-4039(00)95807-6

Treatment of cyclopropylmethanols with pyridinium poly in chlorobenzene-diisopropylamine in the presence of KHF2 gave selectively homoallylic fluorides.

Full text of DOI:10.1016/S0040-4039(00)95807-6

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