Synthesis of a New Bifunctional Hemilabile Ligand by Insertion of PhNCO into a Co-ordinated β-Phosphinoketonate. Crystal Structure of H4CH2NMe2)Pd(Ph2PC>)>

DOI: 10.1039/c39870000488

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 488 - 490 (1987)

Update date:2022-07-30

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Authors:

Bouaoud, Salah-Eddine

Braunstein, Pierre

Grandjean, Daniel

Matt, Dominique

Nobel, Dominique

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Article abstract of DOI:10.1039/c39870000488

The air-stable complex <(o-C6<*>H4CH2NMe2)<*>Pd<*>)Ph>> (1) is an ambident reactive species which readily reacts with PhNCO affording the two isomers (2a) (title complex) and (2b) which formally result from insertion of isocyanate into the C-H bond of the phosphinoketonate; the resulting bifunctional phosphine ligand displays hemilabile character.

Full text of DOI:10.1039/c39870000488

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