Bulletin of the Chemical Society of Japan p. 2024 - 2031 (1989)
Update date:2022-08-04
Topics: Amine Experimental terms Ring Opening Fluorination Ring-Expansion Fluorination Cyclopropanemethanols Metal Fluoride Poly(hydrogen fluoride)-Pyridine Complex
Kanemoto, Shigekazu
Shimizu, Makoto
Yoshioka, Hirosuke
Treatment of cyclopropanemethanols with pyridinium poly(hydrogen fluoride) in the presence of diisopropylamine and KHF2 gave selectively homoallylic fluorides or fluorocyclobutanes according to the mode of substitution of the starting cyclopropanemethanol
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