Chemistry Letters p. 525 - 528 (1987)
Update date:2022-08-04
Topics:
Yamashita, Hiroyuki
The asymmetric ring-opening of symmetrical oxiranes with aniline or trimethylsilyl azide is effectively catalyzed by zinc (2R,3R)-tartrate or cupric (2R,3R)-tartrate to give trans N-phenyl β-amino alcohol or trans O-trimethylsilyl 2-azido alcohols in 17-52percent ee.The latter azido products can be easily converted into optically active trans β-amino alcohols by two-step procedure.
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Doi:10.1007/BF01146183
(1987)Doi:10.1246/bcsj.81.1512
(2008)Doi:10.1135/cccc20071499
(2007)Doi:10.1016/j.tetlet.2009.10.007
(2009)Doi:10.1002/chem.200800536
(2008)Doi:10.1021/ja00280a034
(1986)
