ASYMMETRIC TOTAL SYNTHESIS OF 14(R),15(S)-, 14(S),15(R)-, 14(R),15(R)-, AND 14(S),15(S)-EPOXYEICOSATRIENOIC ACIDS

DOI: 10.1016/S0040-4039(00)85390-3

Source and publish data:

Tetrahedron Letters p. 6031 - 6034 (1986)

Update date:2022-08-03

Topics: Characterization Purification Retrosynthetic analysis Introduction of chirality Scale-Up and Yield Improvement Double Bond Formation

Authors:

Ennis, Michael D.

Baze, Mark E.

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Article abstract of DOI:10.1016/S0040-4039(00)85390-3

The four chiral stereoisomers of 14,15-oxido-5Z,8Z,11Z-eicosatrienoic acid were synthesized.The absolute stereochemistry in each case was derived from an asymmetric epoxidation of E-2-octen-1-ol.

Full text of DOI:10.1016/S0040-4039(00)85390-3

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Product name:(5Z,8Z,11Z)-(14R,15R)-15-Chloro-14-hydroxy-icosa-5,8,11-trienoic acid methyl ester

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