Helvetica Chimica Acta p. 1817 - 1820 (1986)
Update date:2022-09-26
Topics:
Oppolzer, Wolfgang
Schneider, Philippe
Enantiomerically pure β-necrodol (1) and its 1-epimer 16 have been synthesized starting from aldehyde 5.The two key steps are an asymmetric conjugate addition/Mannich reaction tandem (10->12) and a type-II-magnesiumene cyclization/oxidation sequence (14->1 + 16).
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Doi:10.1055/s-1987-27920
(1987)Doi:10.1021/jf803305f
(2009)Doi:10.1021/jo01100a001
(1958)Doi:10.1016/j.tetlet.2021.153057
(2021)Doi:10.1248/cpb.34.3733
(1986)Doi:10.1039/b817196n
(2009)
