Synthesis and Chiroptical Properties of γ-Substituted Rigid and Conformationally Flexible Systems Having 1,3-Diene and α,β-Unsaturated Carbonyl Chromophores. The Planar Diene Rule

DOI: 10.1021/ja00256a027

Source and publish data:

Journal of the American Chemical Society p. 6719 - 6726 (1987)

Update date:2022-07-29

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Authors:

Walborsky, H. M.

Gawronska, K.

Gawronski, J. K.

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Article abstract of DOI:10.1021/ja00256a027

The syntheses of chiral (aS)-(5-hydroxyadamantylidene)- and (aS)-(5-methyladamantylidene)acetaldehyde and the corresponding adamantylidenepropene (rigid system) as well as (aS)-(4-hydroxycyclohexylidene)acetaldehyde and (aS)-(4-hydroxycyclohexylidene)prop

Full text of DOI:10.1021/ja00256a027

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