Organic Letters p. 1207 - 1211 (2019)
Update date:2022-08-03
Topics:
Trost, Barry M.
Tracy, Jacob S.
Yusoontorn, Tas
A vanadium-catalyzed coupling of allenylic alcohols with electrophilic halide sources to form α-halo-α′,β′-unsaturated ketones is described. The process proceeds through a metal enolate formed from the 1,3-transposition of an allenol that is initiated by
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