
Tetrahedron Letters p. 3661 - 3664 (1986)
Update date:2022-09-26
Topics: Intramolecular cyclization Stereochemistry Control Acid-Catalyzed Cyclization
Suzuki, Keisuke
Masuda, Toshiyuki
Fukazawa, Yoshimasa
Tsuchihashi, Gen-ichi
Stereocontrol of C(2)-position of δ-lactones, related to Prelog-Djerassi lactone, is effected via acid-catalyzed cyclization of ketene dithioacetal having an internal OH group (thermodynamic control), which is also applicable to remote asymmetric inductio
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Doi:10.1016/S0040-4039(00)85093-5
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