Tetrahedron Letters p. 1529 - 1532 (1987)
Update date:2022-08-04
Topics:
Tominaga, Yoshinori
Kohra, Shinya
Hosomi, Akira
Thioamides, readily available from aldehydes, sulfur and secondary amines, can be converted to unsymmetrical ketones by the carbophilic addition of organolithiums to the thiocarbonyl group.Reduction of the intermediates with lithium aluminium hydride gives α-alkylated or α-arylated amines.
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Doi:10.1246/bcsj.47.3098
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