Bulletin of the Chemical Society of Japan p. 1027 - 1036 (1987)
Update date:2022-08-05
Topics:
Honda, Yutaka
Ori, Aiichiro
Tsuchihashi, Gen-ichi
(S)-1-Aryl-2-sulfonyloxy-1-alkanone acetals, prepared from natural ethyl (S)-lactate or (S)-valine (chiral sources) by the use of a Grignard reaction, were rearranged under hydrolytic conditions in the presence of a base to give (S)-2-arylalkanoic esters which in general, showed much higher pharmacological activities than their antipodes.
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(1987)
