Bulletin of the Chemical Society of Japan p. 1027 - 1036 (1987)
Update date:2022-08-05
Topics:
Honda, Yutaka
Ori, Aiichiro
Tsuchihashi, Gen-ichi
(S)-1-Aryl-2-sulfonyloxy-1-alkanone acetals, prepared from natural ethyl (S)-lactate or (S)-valine (chiral sources) by the use of a Grignard reaction, were rearranged under hydrolytic conditions in the presence of a base to give (S)-2-arylalkanoic esters which in general, showed much higher pharmacological activities than their antipodes.
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Doi:10.1016/0040-4039(94)88397-1
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(1996)Doi:10.1021/ol802679p
(2009)Doi:10.1055/s-1987-27836
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(1987)
