Transition-Metal Complex Catalyzed Polyfluoroalkylation. A Facile Synthesis of Fluorine-Containing Oxiranes and Enynes

DOI: 10.1246/cl.1987.521

Source and publish data:

Chemistry Letters p. 521 - 524 (1987)

Update date:2022-08-04

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Authors:

Fuchikami, Takamasa

Shibata, Yoshiko

Urata, Hisao

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Article abstract of DOI:10.1246/cl.1987.521

Palladium-catalyzed reaction of polyfluoroalkyl halides with allylic alcohols in the presence of potassium carbonate gives polyfluoroalkylmethyl-substituted oxiranes directly.Perfluoroalkyl-substituted enynes can be also prepared from perfluoroalkyl iodides and terminal alkynes under similar conditions.

Full text of DOI:10.1246/cl.1987.521

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