Tetrahedron Letters p. 409 - 412 (1987)
Update date:2022-07-29
Topics:
Berrada, Said
Metzner, Patrick
1,4-Addition reaction of lithiated methyl dithioacetate with α,β-disubstituted enones affords 5-oxodithioesters.The diastereoselectivity ranges from moderate to high (> 95:5) in favour of the syn isomer.This anti-Houk selectivity arises from an auto-proto
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