Intramolecular Additions of Allylsilanes to Conjugated Dienones. The Synthesis of Three Perforanes

DOI: 10.1021/jo00236a013

Source and publish data:

Journal of Organic Chemistry p. 50 - 68 (1988)

Update date:2022-08-02

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Authors:

Majetich, George

Defauw, Jean

Ringold, Clay

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Article abstract of DOI:10.1021/jo00236a013

Intramolecular addition of allylsilanes to 3-vinylcycloalkenones provides a powerful means of constructing functionalized 5-5, 5-7, 6-5, and 6-7 bicyclic ring systems.Our results reveal a divergence in reactivity, dependent on reaction catalyst and substr

Full text of DOI:10.1021/jo00236a013

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