REDUCTIVE CLEAVAGES OF α,β-ALKYNYL ACETALS. NEW ROUTE TO OPTICALLY PURE PROPALGYLIC ALCOHOLS

DOI: 10.1016/S0040-4039(00)84155-6

Source and publish data:

Tetrahedron Letters p. 983 - 986 (1986)

Update date:2022-08-05

Topics:

Authors:

Ishihara, Kazuaki

Mori, Atsunori

Arai, Isao

Yamamoto, Hisashi

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)84155-6

Optically pure propargylic alcohols are obtained by the reductive cleavages of chiral α,β-alkynyl acetals with organoaluminum reagent followed by removal of chiral auxiliary.

Full text of DOI:10.1016/S0040-4039(00)84155-6

Products guided by the article

Product name:(2R,4R)-4-((S)-1-Cyclohexyl-but-2-ynyloxy)-pentan-2-ol

Cas No:111555-96-5

R&D Labs maybe for 111555-96-5

Hangzhou Yingshanhua Pigment Chemicals Co.,Ltd.

Contact:+86-0150-58101658

Address:Nanyang Economic DevelopmentZong,Xiaoshan,Hangzhou,China
Jiangsu Jiuri Chemical Co.,Ltd.

Contact:+86-519-82118868

Address:Tianwang Town, Jurong City, Jiangsu Province, China
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Shijiazhuang Haitian Amino Acid Co., Ltd.

Contact:+86-311-88908111

Address:Shijiazhuang Hebei province,China
ShenZhen InnoSyn Biotech Co.,Ltd

website:http://www.innosyns.com

Contact:+86-755-28351685

Address:Floor 5 & 6, Building A1, HAIKEXING Strategic Innovative Industrial Park, 16 BaoShan Road, PingShan District

Relevant to this article

Deoxygenation of Tertriary Alcohols Using Raney Nickel

Doi:10.1021/jo00237a041
(1988)
N-Aryl 3-Halogenated Azetidin-2-ones and Benzocarbacephems, Inhibitors of β-Lactamases

Doi:10.1021/jm00397a018
(1988)
Substitution effects in intramolecular aziridine-allylsilane cyclizations

Doi:10.1016/j.tet.2008.11.043
(2009)
Phosphonolipids. 3. Phosphonic acid analogues of phosphatidylinositol and related materials

Doi:10.1139/v92-268
(1992)
1a">Synthesis of C-2"&β- and C-2"&α-Fluoro Avermectin B_1a

Doi:10.1039/c39870000368
(1987)
SYNTHESIS AND STUDY OF TAUTOMERIC PROPERTIES OF 2-(5-R-2-FURYL)THIAZOLIN-4-ONES

Doi:10.1007/BF00761997
(1987)

Article Doi