REDUCTIVE CLEAVAGES OF α,β-ALKYNYL ACETALS. NEW ROUTE TO OPTICALLY PURE PROPALGYLIC ALCOHOLS

DOI: 10.1016/S0040-4039(00)84155-6

Source and publish data:

Tetrahedron Letters p. 983 - 986 (1986)

Update date:2022-08-05

Topics:

Authors:

Ishihara, Kazuaki

Mori, Atsunori

Arai, Isao

Yamamoto, Hisashi

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Article abstract of DOI:10.1016/S0040-4039(00)84155-6

Optically pure propargylic alcohols are obtained by the reductive cleavages of chiral α,β-alkynyl acetals with organoaluminum reagent followed by removal of chiral auxiliary.

Full text of DOI:10.1016/S0040-4039(00)84155-6

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