ASYMMETRIC AZA-CLAISEN REARRANGEMENT: SYNTHESIS OF (+)-DIHYDROPALLESCENSIN-2

DOI: 10.1016/S0040-4039(00)95903-3

Source and publish data:

Tetrahedron Letters p. 1031 - 1034 (1987)

Update date:2022-08-04

Topics:

Authors:

Kurth, Mark J.

Soares, Christopher J.

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Article abstract of DOI:10.1016/S0040-4039(00)95903-3

Synthetic confirmation of the C(1')-(S)-configuration of (+)-dihydropallescensin-2 (1) is reported, the key reaction being a chiron-mediated asymmetric aza-Claisen rearrangement (6<*>7).

Full text of DOI:10.1016/S0040-4039(00)95903-3

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