Chemistry Letters p. 811 - 814 (1987)
Update date:2022-07-31
Topics:
Kubo, Yasuo
Okusako, Kensen
Araki, Takeo
Irradiation of 1,2-naphthalenedicarboxylic thioanhydride (5a) or its 2,3-isomer with alkenes in acetonitrile gave naphthothiepindiones by insertion of alkenes into C(=O)-S bond of the thioanhydride.Reactions of 5a with cis- and trans-2-butene were stereospecific, demonstrating that the insertion was caused from the singlet excited state of 5a.
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Doi:10.1021/acs.jmedchem.0c00388
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