A Convenient Preparation of α-(p-Hydroxy- or p-Aminophenyl) Carbonyl Compounds. Addition-Reduction Reaction of Tin(II) Enolate with p-Benzoquinone and Its Mono-N-tosylimino Derivative

DOI: 10.1246/cl.1987.479

Source and publish data:

Chemistry Letters p. 479 - 482 (1987)

Update date:2022-08-05

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Authors:

Mukaiyama, Teruaki

Clark, Richard S. J.

Iwasawa, Nobuharu

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Article abstract of DOI:10.1246/cl.1987.479

Tin(II) enolates react with p-benzoquinone and its mono-N-tosylimino derivative to give 1,2-adducts in good yield.These can be reduced in situ to α-(p-hydroxy- or p-aminophenyl) carbonyl derivatives by addition of dichloromethylsilane and dimethylaminopyr

Full text of DOI:10.1246/cl.1987.479

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