
Tetrahedron p. 5953 - 5958 (1988)
Update date:2022-08-03
Topics:
Baldwin, Jack E.
Adlington, Robert M.
Kang, Tae Won
Lee, Eun
Schofield, Christopher J.
Reaction of a 2β-bromomethyl penam with triphenyltin hydride gave, via ring expansion of the derived 2β-methyl radical, the corresponding cepham system; a similar process may be in operation during the biosynthetic ring expansion of penicillin N to deacet
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