1,1,1-Trichloro-2,2,2-trimethyldisilane: Reagent for Stereospecific Silylation of ?-Allylpalladium Complexes

DOI: 10.1039/c39870000398

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 398 - 399 (1987)

Update date:2022-08-03

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Authors:

Hayashi, Tamio

Yamamoto, Akihiro

Iwata, Takao

Ito, Yoshihiko

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Article abstract of DOI:10.1039/c39870000398

Reaction of optically active ?-allylpalladium complexes with Cl3SiSiMe3or Cl2PhSiSiMe3 in the presence of triphenylphosphine was found to proceed with retention of configuration to give optically allylsilanes in high yields.

Full text of DOI:10.1039/c39870000398

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