
Tetrahedron Letters p. 1051 - 1054 (1987)
Update date:2022-07-29
Topics:
Henegar, Kevin E.
Winkler, Jeffrey D.
The generality of the intramolecular dioxolenone photocycloaddition we have described depends on the availability of the requisite functionalized dioxolenones.We report herein a general approach to the preparation of dioxolenones, via carboxylation of ketone enolates with anisyl cyanoformate and condensation of the resulting ketoesters with acetone.
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