Journal of Organic Chemistry p. 3383 - 3389 (1989)
Update date:2022-08-04
Topics:
Yoshida, Jun-ichi
Nakatani, Shogo
Sakaguchi, Kazuhiko
Isoe, Sachihiko
Formal <2 + 2 + 2> cycloaddition of molecular oxygen, 1,3-diketones, and olefins took place by electrochemical oxidation.A catalytic amount of electricity was sufficient for the reaction, and an electroinitiated radical chain mechanism was proposed.The reaction was also initiated by a radical initiator.The resulting cyclic peroxides reacted with acids and some reducing agents such as ferrous sulfate, thiurea, and copper(I) chloride to give oxygen-oxygen bond cleavage products.
View MoreHenan Techway Chemical Co.,Ltd.
website:http://www.techwaychem.com
Contact:+86-371-66380080
Address:No.27 Shunhe Road,
WUXI KINGHAN BIO-MEDICAL&CHEMICAL INC.
Contact:13861062998
Address:Room 1316,No.1619 Huishan Avenue,Wuxi,China
Qingdao Kingway Pharmtech Co., Ltd.
Contact:86-532-87118899
Address:No. 88, Middle Haixi Road, Jiaonan City, Qingdao, China
Contact:13357117572
Address:No.149 Shiji dadao Road.
Yangzhou Siyu Chemical Co.,Ltd.
Contact:+86-514-87325867 13358126196
Address:Room 620 Exposition Pavilion，No. 98 Huaihai Road,Guangling District，Yangzhou City, Jiangsu Province
Doi:10.3987/R-1986-12-3385
(1986)Doi:10.1002/recl.19871060505
(1987)Doi:10.1016/S0040-4020(01)86840-X
(1987)Doi:10.1021/ja01464a038
(1961)Doi:10.1016/j.tetlet.2008.11.111
(2009)Doi:10.1021/jm00398a025
(1988)
