A Novel One-Flask Cyclopropanation and Vinylcyclopropanation Method for α-Enones. Copper(I)-Induced γ-Thiophenoxide Removal from Conjugate Adducts

DOI: 10.1021/jo00237a053

Source and publish data:

Journal of Organic Chemistry p. 457 - 460 (1988)

Update date:2022-08-05

Topics:

Authors:

Cohen, Theodore

Myers, Michael

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00237a053

A novel concept for performing a one-flak cyclopropanation of conjugated enones consists of conjugate addition of an appropriate phenylthio-stabilized organolithium compound followed by treatment of the resulting enolate anion with cuprous trifluoromethan

Full text of DOI:10.1021/jo00237a053

Products guided by the article

Product name:3',4'-dihydro-1'-oxo-2,2-bis(phenylthio)spiro

Cas No:112022-55-6

R&D Labs maybe for 112022-55-6

Fuxin Jintelai Fluorin Chemical Co., Ltd.

Contact:+86-0418-8229599

Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
ORCHID CHEMICAL SUPPLIES LTD

website:http://www.orchid-chem.com

Contact:+86-571-85395792

Address:607, North Zhongshan Road, Hangzhou 310000 China
Weinan Rigel Pharm Co., Ltd.

Contact:+86-913-2223392

Address:No. 32, Xinanjing Road, Weinan City, Shaanxi Province, 714000, China
Shanghai Hope Chem Co., Ltd

website:http://www.hope-chem.com

Contact:86-21-58090396-805

Address:Floor 4, Building 5, No.588 Tianxiong Road, Zhoupu International Medical Zone, ShangHai, China
Shanghai Massive Chemical Technology Co., Ltd.

website:http://www.massivechem.com/

Contact:+86 21 34943721

Address:Room 435, 4th floor, Building 9, No. 2568 Gudai Road,Minhang District, Shanghai,

Relevant to this article

Synthesis of chaetomellic anhydride A, A potent inhibitor of ras protein farnesyltransferase

Doi:10.3987/COM-08-S(F)16
(2009)
FIVE-MEMBERED 2,3-DIOXO HETEROCYCLES. 2. SYNTHESIS AND <1,5>-SIGMATROPIC REARRANGEMENT OF 4-ACYL-3-DIPHENYLMETHOXY-1,5-DIPHENYL-2,5-DIHYDROPYRROL-2-ONES

Doi:10.1007/BF00476378
(1987)
Expedient preparation of all isomers of 2-aminocyclobutanecarboxylic acid in enantiomerically pure form

Doi:10.1021/jo900175p
(2009)
Design, synthesis, and biological evaluation of 1,5-benzothiazepine-4-one derivatives targeting factor VIIa/tissue factor

Doi:10.1016/j.bmcl.2009.01.039
(2009)
MILD BASIC AND HIGHLY SELECTIVE HYDROLYSIS OF AN ARYL-ALKYL 1-H-PHOSPHONATE DIESTER: PREPARATION OF THE MONO-1-H-PHOSPHONYLATED DIPEPTIDE Z-Ser(OPO2H2)-Tyr(OH)NH2.

Doi:10.1016/S0040-4039(00)96539-0
(1987)
Aminofurazans as potent inhibitors of AKT kinase

Doi:10.1016/j.bmcl.2009.01.002
(2009)

Article Doi