AN ANION-PROMOTED REARRANGEMENT OF 2-(o- AND p-NITROBENZYLOXY)TROPONES TO α-HYDROXYLATED 2-(o- AND p-NITROBENZYL)TROPONES. A READY INTRODUCTION OF ARALKYL GROUP INTO THE TROPONOID NUCLEUS

DOI: 10.1246/cl.1986.593

Source and publish data:

Chemistry Letters p. 593 - 596 (1986)

Update date:2022-09-26

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Authors:

Takeshita, Hitoshi

Mori, Akira

Suizu, Hiroshi

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Article abstract of DOI:10.1246/cl.1986.593

During the preparation of 2-(o- and p-nitrobenzyloxy)tropones from o- and p-nitrobenzyl chlorides and potassium tropolonate, a concomittant formation of α-hydroxylated 2-(o- and p-nitrobenzyl)tropones and 3-(o- and p-nitrobenzyl)tropolones was recognized.

Full text of DOI:10.1246/cl.1986.593

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