Journal of the Chemical Society. Chemical communications p. 1160 - 1161 (1988)
Update date:2022-08-04
Topics:
Ahmad-Junan, S. Asiah
Whiting, Donald A.
The (+/-)-6aα, 12aα, 12α-chromanochromanol acetate (11; R=Ac), representing the core structure of the insecticidal rotenoid alcohol (2), has been synthesised in six steps from the chromone (4); the cis,cis-stereochemistry is obtained in an intramolecular 6-exo aryl radical addition.
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(1987)Doi:10.1038/nmat4910
(2017)
