Chemistry Letters p. 235 - 236 (1987)
Update date:2022-08-04
Topics:
Damrauer, Robert
Weber, William P.
Manuel, Georges
Ion-molecule reactions between fluoride and 1,3,3-trimethyl-6-oxa-3-silabicyclo<3.1.0>hexane, 2,7-dimethyl-2,3:7,8-diepoxy-5-spiro<4.4>nonane, and 3,3-dimethyl-6-oxa-3-germabicyclo<3.1.0>hexane are reported.Attack by fluoride at either silicon or germanium results in loss of either isoprene or butadiene, respectively.An analogous reaction with amide ion is reported.
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Doi:10.1016/S0040-4039(00)95680-6
(1987)Doi:10.1021/ol802838v
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(1990)
