EFFECT OF MAGNESIUM CATION ON HIGH SELECTIVE 1,5-ASYMMETRIC REDUCTION OF C2-SYMMETRIC ACETALKETONES

DOI: 10.1016/S0040-4039(00)95390-5

Source and publish data:

Tetrahedron Letters p. 1671 - 1672 (1987)

Update date:2022-07-30

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Authors:

Hasagewa, Kazuo

Matsuda, Fuyuhiko

Yanagiya, Mitsutoshi

Matsumoto, Takeshi

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Article abstract of DOI:10.1016/S0040-4039(00)95390-5

In LiAlH4-reduction of C₂-symmetric acetalketones, 1,5-asymmetric induction took place in good optical yields by the addition of LiBr or MgBr2.In some cases, induction proceeded in a reverse manner under the influence of added MgBr2.

Full text of DOI:10.1016/S0040-4039(00)95390-5

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