The Synthesis and X-Ray Crystal Structures of Homoleptic Tetrahedral Aryls of Osmium(IV) and of Cyclohexyls of Ruthenium(IV), Osmium(IV), and Chromium(IV)

DOI: 10.1039/DT9870000557

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 557 - 562 (1987)

Update date:2022-07-30

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Authors:

Stavropoulos, Pericles

Savage, Paul D.

Tooze, Robert P.

Wilkinson, Geoffrey

Hussain, Bilquis

et al. et al.

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Article abstract of DOI:10.1039/DT9870000557

The interactions of o-tolylmagnesium bromide or AlPh3(OEt2) with osmium tetraoxide leads to the isolation of the homoleptic, tetrahedral osmium(IV) compounds OsR4 (R = C6H4Me-o or C6H5).Thermally stable M(C6H11)4 compounds (M = Ru, Os, or Cr; C6H11 = cycl

Full text of DOI:10.1039/DT9870000557

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