Generation of the Dianion from Tetrasilabicyclobutane Derivatives

DOI: 10.1246/cl.1987.227

Source and publish data:

Chemistry Letters p. 227 - 230 (1987)

Update date:2022-08-05

Topics:

Authors:

Kawase, Takeshi

Batcheller, Scott A.

Masamune, Satoru

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Article abstract of DOI:10.1246/cl.1987.227

Reductive cyclization of R2ClSi-SiCl2R' with 5 equiv. of lithium naphthalenide followed by aqueous workup provides the corresponding cyclotetrasilane <(R2SiSiHR')2>.Similar treatment converts RCl2SiSiClHR into a stereoisomeric mixture of cyclotetrasilanes

Full text of DOI:10.1246/cl.1987.227

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