Journal of the Chemical Society. Chemical communications p. 513 - 514 (1987)
Update date:2022-08-05
Topics:
Jousseaume, B.
Villeneuve, P.
Electriphilic cleavage of mixed-functionality tetraorganotin compounds by iodine reveals a complete reversal of the usually observed selectivity; i.e. alkyltin-carbon bonds are broken in preference to aryl- or vinyl-tin-carbon bonds; this unexpected result is explained by intramolecular assistance at tin.
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Doi:10.1002/anie.200804487
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