Chemistry Letters p. 1923 - 1926 (1987)
Update date:2022-08-04
Topics:
Chen, Kau-Ming
Gunderson, Karl G.
Hardtmann, Goetz E.
Prasad, Kapa
Repic, Oljan
Shapiro, Michael J.
An in situ method for generating Et2BOCH3 from triethylborane and methanol without using any other catalysts is described.Using the Et2BOCH3 thus generated as a chelating agent, syn 1,3-diols are prepared in > 98 percent stereochemical purity by reducing β-hydroxy-ketones with sodium borohydride
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Doi:10.1055/s-0028-1083249
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(2009)
